Hi Eric,
we are just in the process of updating some of our cluster docs, see
http://www.scalix.com/wiki/index.php?title=HowTos/HA for a preview. I believe this should give you what you need.
On the storage side, we recommend against using NFS as a storage technology and in fact won't support it, if this is what you are referring to when talking about a file server. This is because NFS is performance optimized for large-bllock read-mostly access like on a home share server or so - where the needs of a transaction-based email system like Scalix are quite the opposite (small chunks of data, lots of writes, synchrnous access, locking).
For shared storage in a cluster, you are much better off using a SAN, FibreChannel or SCSI based disk arrays or external enclosures.
I would recommend that you get in touch with us and discuss the exact details of your setup with one of our product specialists who will be glad to help you.
Cheers,
Florian.